When to run a blank using ICP-MSHow are samples prepared for analysis with ICP-OES? Can it analyse gases?(How) Does ICP-OES determine the quantity of detected elements, or just their occurance in the sample?ICP-OES data treatment: correct for dilution and inweight, the unitsAbsorption Spectrum Using a SpectrophotometerAnalysis of salts using color change when heatedProblem digesting sample for Ti analysis using ICP-OESHome science optical absorption test for approximate caffeine quantity in coffee?NIOSH 7300 - ICP OES calculationDoes ICP-OES detect molecules in suspension?What happens to chromium (as Cr2O7-) in the plasma of the ICP?
Asahi Dry Black beer can
Where did the extra Pym particles come from in Endgame?
Why was Germany not as successful as other Europeans in establishing overseas colonies?
Has any spacecraft ever had the ability to directly communicate with civilian air traffic control?
Need help understanding harmonic series and intervals
Lock in SQL Server and Oracle
Did Henry V’s archers at Agincourt fight with no pants / breeches on because of dysentery?
Transfer over $10k
Options leqno, reqno for documentclass or exist another option?
Airbnb - host wants to reduce rooms, can we get refund?
Historically, were women trained for obligatory wars? Or did they serve some other military function?
Stark VS Thanos
How to creep the reader out with what seems like a normal person?
Do I have to worry about players making “bad” choices on level up?
Any examples of headwear for races with animal ears?
What is the range of this combined function?
A non-technological, repeating, visible object in the sky, holding its position in the sky for hours
Pulling the rope with one hand is as heavy as with two hands?
Can a creature tell when it has been affected by a Divination wizard's Portent?
Toggle Overlays shortcut?
Why do TACANs not have a symbol for compulsory reporting?
Does jamais mean always or never in this context?
Illegal assignment from SObject to Contact
Will tsunami waves travel forever if there was no land?
When to run a blank using ICP-MS
How are samples prepared for analysis with ICP-OES? Can it analyse gases?(How) Does ICP-OES determine the quantity of detected elements, or just their occurance in the sample?ICP-OES data treatment: correct for dilution and inweight, the unitsAbsorption Spectrum Using a SpectrophotometerAnalysis of salts using color change when heatedProblem digesting sample for Ti analysis using ICP-OESHome science optical absorption test for approximate caffeine quantity in coffee?NIOSH 7300 - ICP OES calculationDoes ICP-OES detect molecules in suspension?What happens to chromium (as Cr2O7-) in the plasma of the ICP?
$begingroup$
I am currently writing a paper for my Advanced Analytical Chemistry course, and the topic I am writing on is the analysis of Arsenic in drinking water. The EPA's literature describes how to perform this method but does not describe how many samples should be taken or when and where blanks should be used. The three blanks required for analysis are the rinse blank, calibration blank, and the laboratory reagent blank. My question is, if we assume we are analyzing twenty water samples using ICP-MS, when should each type of blank be run?
analytical-chemistry
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
add a comment |
$begingroup$
I am currently writing a paper for my Advanced Analytical Chemistry course, and the topic I am writing on is the analysis of Arsenic in drinking water. The EPA's literature describes how to perform this method but does not describe how many samples should be taken or when and where blanks should be used. The three blanks required for analysis are the rinse blank, calibration blank, and the laboratory reagent blank. My question is, if we assume we are analyzing twenty water samples using ICP-MS, when should each type of blank be run?
analytical-chemistry
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
add a comment |
$begingroup$
I am currently writing a paper for my Advanced Analytical Chemistry course, and the topic I am writing on is the analysis of Arsenic in drinking water. The EPA's literature describes how to perform this method but does not describe how many samples should be taken or when and where blanks should be used. The three blanks required for analysis are the rinse blank, calibration blank, and the laboratory reagent blank. My question is, if we assume we are analyzing twenty water samples using ICP-MS, when should each type of blank be run?
analytical-chemistry
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
I am currently writing a paper for my Advanced Analytical Chemistry course, and the topic I am writing on is the analysis of Arsenic in drinking water. The EPA's literature describes how to perform this method but does not describe how many samples should be taken or when and where blanks should be used. The three blanks required for analysis are the rinse blank, calibration blank, and the laboratory reagent blank. My question is, if we assume we are analyzing twenty water samples using ICP-MS, when should each type of blank be run?
analytical-chemistry
analytical-chemistry
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
asked 4 hours ago
Dillon StetlerDillon Stetler
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
asked 4 hours ago
Dillon StetlerDillon Stetler
111
asked 4 hours ago
Dillon StetlerDillon Stetler
111
111
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
New contributor
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
Dillon Stetler is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
add a comment |
add a comment |
1 Answer
1
active
oldest
votes
$begingroup$
This terminology is specific to EPA and it is not universal, because there are so many legal issues associated with any environmental analysis. They have to be extremely careful at each and every step (it may cost someone millions because of a wrong analytical result). Hence the reason for various "blanks." The language of those methods is official and the steps are highly detailed. Hence these robust methods can be defended legally using the terminologies used in the methods.
While preparing a calibration curve by ICP or any other spectrochemical technique, there can be only one blank, which sets the baseline reading. One would run this blank and 5-6 standards. So which blank is this? By EPA nomenclature, this is the calibration blank, which is defined by them as "Calibration Blank – A blank solution containing all of the reagents in the same concentration as those used in the analytical sample preparation. This blank is not subject to the preparation method." Pretty much standard definition.
So what are the other plenty of blank solutions doing? They are used for quality control after the calibration to check the accuracy of the instrument, method, operator etc. One can test them right after performing the calibration process. See how specific the directions are:
a) Laboratory Reagent Blank (LRB) – An aliquot of ASTM Type I water that is treated exactly as a sample including exposure to all labware, equipment, solvents, reagents and internal standards that are used with other samples. The LRB is used to determine if method analytes or other interferences are present in the laboratory environment, the reagents or apparatus.
b) The rinse blank, as the name indicates for rinsing the lines. You should discuss how complex the sample introduction system is in ICPs. >90% sample is wasted and a small fraction goes to the plasma.
EPA defines it as well. The rinse blank should flush the system between solution changes for blanks, standards, and samples. Allow sufficient rinse time (~ 1 min) to remove traces of the previous sample. Solutions should aspirate for at least 30 seconds prior to the acquisition of data to establish equilibrium
Reference: this detailed report with terminologies
(ICP-MS) with - EPA: https://www3.epa.gov/ttnamti1/files/ambient/pb/EQL-0512-202.pdf
answered 1 hour ago
M. FarooqM. Farooq
2,125111
$endgroup$
add a comment |
Your Answer
StackExchange.ready(function()
var channelOptions =
tags: "".split(" "),
id: "431"
;
initTagRenderer("".split(" "), "".split(" "), channelOptions);
StackExchange.using("externalEditor", function()
// Have to fire editor after snippets, if snippets enabled
if (StackExchange.settings.snippets.snippetsEnabled)
StackExchange.using("snippets", function()
createEditor();
);
else
createEditor();
);
function createEditor()
StackExchange.prepareEditor(
heartbeatType: 'answer',
autoActivateHeartbeat: false,
convertImagesToLinks: false,
noModals: true,
showLowRepImageUploadWarning: true,
reputationToPostImages: null,
bindNavPrevention: true,
postfix: "",
imageUploader:
brandingHtml: "Powered by u003ca class="icon-imgur-white" href="https://imgur.com/"u003eu003c/au003e",
contentPolicyHtml: "User contributions licensed under u003ca href="https://creativecommons.org/licenses/by-sa/3.0/"u003ecc by-sa 3.0 with attribution requiredu003c/au003e u003ca href="https://stackoverflow.com/legal/content-policy"u003e(content policy)u003c/au003e",
allowUrls: true
,
onDemand: true,
discardSelector: ".discard-answer"
,immediatelyShowMarkdownHelp:true
);
);
Dillon Stetler is a new contributor. Be nice, and check out our Code of Conduct.
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
StackExchange.ready(
function ()
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f114513%2fwhen-to-run-a-blank-using-icp-ms%23new-answer', 'question_page');
);
Post as a guest
Required, but never shown
1 Answer
1
active
oldest
votes
1 Answer
1
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
This terminology is specific to EPA and it is not universal, because there are so many legal issues associated with any environmental analysis. They have to be extremely careful at each and every step (it may cost someone millions because of a wrong analytical result). Hence the reason for various "blanks." The language of those methods is official and the steps are highly detailed. Hence these robust methods can be defended legally using the terminologies used in the methods.
While preparing a calibration curve by ICP or any other spectrochemical technique, there can be only one blank, which sets the baseline reading. One would run this blank and 5-6 standards. So which blank is this? By EPA nomenclature, this is the calibration blank, which is defined by them as "Calibration Blank – A blank solution containing all of the reagents in the same concentration as those used in the analytical sample preparation. This blank is not subject to the preparation method." Pretty much standard definition.
So what are the other plenty of blank solutions doing? They are used for quality control after the calibration to check the accuracy of the instrument, method, operator etc. One can test them right after performing the calibration process. See how specific the directions are:
a) Laboratory Reagent Blank (LRB) – An aliquot of ASTM Type I water that is treated exactly as a sample including exposure to all labware, equipment, solvents, reagents and internal standards that are used with other samples. The LRB is used to determine if method analytes or other interferences are present in the laboratory environment, the reagents or apparatus.
b) The rinse blank, as the name indicates for rinsing the lines. You should discuss how complex the sample introduction system is in ICPs. >90% sample is wasted and a small fraction goes to the plasma.
EPA defines it as well. The rinse blank should flush the system between solution changes for blanks, standards, and samples. Allow sufficient rinse time (~ 1 min) to remove traces of the previous sample. Solutions should aspirate for at least 30 seconds prior to the acquisition of data to establish equilibrium
Reference: this detailed report with terminologies
(ICP-MS) with - EPA: https://www3.epa.gov/ttnamti1/files/ambient/pb/EQL-0512-202.pdf
answered 1 hour ago
M. FarooqM. Farooq
2,125111
$endgroup$
add a comment |
$begingroup$
This terminology is specific to EPA and it is not universal, because there are so many legal issues associated with any environmental analysis. They have to be extremely careful at each and every step (it may cost someone millions because of a wrong analytical result). Hence the reason for various "blanks." The language of those methods is official and the steps are highly detailed. Hence these robust methods can be defended legally using the terminologies used in the methods.
While preparing a calibration curve by ICP or any other spectrochemical technique, there can be only one blank, which sets the baseline reading. One would run this blank and 5-6 standards. So which blank is this? By EPA nomenclature, this is the calibration blank, which is defined by them as "Calibration Blank – A blank solution containing all of the reagents in the same concentration as those used in the analytical sample preparation. This blank is not subject to the preparation method." Pretty much standard definition.
So what are the other plenty of blank solutions doing? They are used for quality control after the calibration to check the accuracy of the instrument, method, operator etc. One can test them right after performing the calibration process. See how specific the directions are:
a) Laboratory Reagent Blank (LRB) – An aliquot of ASTM Type I water that is treated exactly as a sample including exposure to all labware, equipment, solvents, reagents and internal standards that are used with other samples. The LRB is used to determine if method analytes or other interferences are present in the laboratory environment, the reagents or apparatus.
b) The rinse blank, as the name indicates for rinsing the lines. You should discuss how complex the sample introduction system is in ICPs. >90% sample is wasted and a small fraction goes to the plasma.
EPA defines it as well. The rinse blank should flush the system between solution changes for blanks, standards, and samples. Allow sufficient rinse time (~ 1 min) to remove traces of the previous sample. Solutions should aspirate for at least 30 seconds prior to the acquisition of data to establish equilibrium
Reference: this detailed report with terminologies
(ICP-MS) with - EPA: https://www3.epa.gov/ttnamti1/files/ambient/pb/EQL-0512-202.pdf
answered 1 hour ago
M. FarooqM. Farooq
2,125111
$endgroup$
add a comment |
$begingroup$
This terminology is specific to EPA and it is not universal, because there are so many legal issues associated with any environmental analysis. They have to be extremely careful at each and every step (it may cost someone millions because of a wrong analytical result). Hence the reason for various "blanks." The language of those methods is official and the steps are highly detailed. Hence these robust methods can be defended legally using the terminologies used in the methods.
While preparing a calibration curve by ICP or any other spectrochemical technique, there can be only one blank, which sets the baseline reading. One would run this blank and 5-6 standards. So which blank is this? By EPA nomenclature, this is the calibration blank, which is defined by them as "Calibration Blank – A blank solution containing all of the reagents in the same concentration as those used in the analytical sample preparation. This blank is not subject to the preparation method." Pretty much standard definition.
So what are the other plenty of blank solutions doing? They are used for quality control after the calibration to check the accuracy of the instrument, method, operator etc. One can test them right after performing the calibration process. See how specific the directions are:
a) Laboratory Reagent Blank (LRB) – An aliquot of ASTM Type I water that is treated exactly as a sample including exposure to all labware, equipment, solvents, reagents and internal standards that are used with other samples. The LRB is used to determine if method analytes or other interferences are present in the laboratory environment, the reagents or apparatus.
b) The rinse blank, as the name indicates for rinsing the lines. You should discuss how complex the sample introduction system is in ICPs. >90% sample is wasted and a small fraction goes to the plasma.
EPA defines it as well. The rinse blank should flush the system between solution changes for blanks, standards, and samples. Allow sufficient rinse time (~ 1 min) to remove traces of the previous sample. Solutions should aspirate for at least 30 seconds prior to the acquisition of data to establish equilibrium
Reference: this detailed report with terminologies
(ICP-MS) with - EPA: https://www3.epa.gov/ttnamti1/files/ambient/pb/EQL-0512-202.pdf
answered 1 hour ago
M. FarooqM. Farooq
2,125111
$endgroup$
This terminology is specific to EPA and it is not universal, because there are so many legal issues associated with any environmental analysis. They have to be extremely careful at each and every step (it may cost someone millions because of a wrong analytical result). Hence the reason for various "blanks." The language of those methods is official and the steps are highly detailed. Hence these robust methods can be defended legally using the terminologies used in the methods.
While preparing a calibration curve by ICP or any other spectrochemical technique, there can be only one blank, which sets the baseline reading. One would run this blank and 5-6 standards. So which blank is this? By EPA nomenclature, this is the calibration blank, which is defined by them as "Calibration Blank – A blank solution containing all of the reagents in the same concentration as those used in the analytical sample preparation. This blank is not subject to the preparation method." Pretty much standard definition.
So what are the other plenty of blank solutions doing? They are used for quality control after the calibration to check the accuracy of the instrument, method, operator etc. One can test them right after performing the calibration process. See how specific the directions are:
a) Laboratory Reagent Blank (LRB) – An aliquot of ASTM Type I water that is treated exactly as a sample including exposure to all labware, equipment, solvents, reagents and internal standards that are used with other samples. The LRB is used to determine if method analytes or other interferences are present in the laboratory environment, the reagents or apparatus.
b) The rinse blank, as the name indicates for rinsing the lines. You should discuss how complex the sample introduction system is in ICPs. >90% sample is wasted and a small fraction goes to the plasma.
EPA defines it as well. The rinse blank should flush the system between solution changes for blanks, standards, and samples. Allow sufficient rinse time (~ 1 min) to remove traces of the previous sample. Solutions should aspirate for at least 30 seconds prior to the acquisition of data to establish equilibrium
Reference: this detailed report with terminologies
(ICP-MS) with - EPA: https://www3.epa.gov/ttnamti1/files/ambient/pb/EQL-0512-202.pdf
answered 1 hour ago
M. FarooqM. Farooq
2,125111
answered 1 hour ago
M. FarooqM. Farooq
2,125111
answered 1 hour ago
M. FarooqM. Farooq
2,125111
answered 1 hour ago
M. FarooqM. Farooq
2,125111
2,125111
add a comment |
add a comment |
Dillon Stetler is a new contributor. Be nice, and check out our Code of Conduct.
Dillon Stetler is a new contributor. Be nice, and check out our Code of Conduct.
Dillon Stetler is a new contributor. Be nice, and check out our Code of Conduct.
Dillon Stetler is a new contributor. Be nice, and check out our Code of Conduct.
Thanks for contributing an answer to Chemistry Stack Exchange!
- Please be sure to answer the question. Provide details and share your research!
But avoid …
- Asking for help, clarification, or responding to other answers.
- Making statements based on opinion; back them up with references or personal experience.
Use MathJax to format equations. MathJax reference.
To learn more, see our tips on writing great answers.
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
StackExchange.ready(
function ()
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f114513%2fwhen-to-run-a-blank-using-icp-ms%23new-answer', 'question_page');
);
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
